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The first examples of [3+2] cycloadditions with the participation of (E)‐3,3,3‐tribromo‐1‐nitroprop‐1‐ene
Authors:
- Karolina Zawadzińska,
- Zuzanna Gadocha,
- Kamila Pabian,
- Aneta Wróblewska,
- Ewelina Wielgus,
- Radomir Jasiński
Abstract
The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving TBMN and diarylnitrones realized with full regio- and stereoselectivity lead to respective 3,4-cis-4,5-trans-4-nitroisoxazolidines. The regioselecticity and the molecular mechanism of title processes was analyzed on the basis of the advanced DFT computational study.
- Record ID
- CUTc908505a671c4e0c9c57b2f34aec76f0
- Publication categories
- ;
- Author
- Journal series
- Materials, ISSN , e-ISSN 1996-1944, Biweekly
- Issue year
- 2022
- Vol
- 15
- No
- 21
- Pages
- [1-9]
- Article number
- 7584
- Other elements of collation
- rys.; tab.; Bibliografia (na s.) - 7-9; Bibliografia (liczba pozycji) - 39; Oznaczenie streszczenia - Abstr.; Numeracja w czasopiśmie - Vol. 15, Iss. 21
- Substantive notes
- This article belongs to the Special Issue: Recent Advances in the Chemistry of Halogens
- Keywords in English
- [3+2] cycloaddition, 3,3,3-tribromo-1-nitroprop-1-ene, nitrones, molecular mechanism, molecular electron density theory
- ASJC Classification
- DOI
- DOI:10.3390/ma15217584 Opening in a new tab
- URL
- https://www.mdpi.com/1996-1944/15/21/7584 Opening in a new tab
- Language
- eng (en) English
- License
- Score (nominal)
- 140
- Score source
- journalList
- Score
- Publication indicators
- Additional fields
- Indeksowana w: Web of Science, Scopus
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUTc908505a671c4e0c9c57b2f34aec76f0/
- URN
urn:pkr-prod:CUTc908505a671c4e0c9c57b2f34aec76f0
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.