Visible light induced high resolution and swift 3D printing system by halogen atom transfer
Authors:
- Wiktoria Tomal,
- Huseyin Cem Kiliclar,
- Pawel Fiedor,
- Joanna Ortyl,
- Yusuf Yagci
Abstract
3D printing technology offers solutions for numerous needs in industry andthe daily life of individuals. In recent years, most research efforts have focusedon this technology as the market share has grown and requirements havebecome specified in their related fields. In this work, a novel visible lightinduced 3D printing system with high resolution and short printing timeusing dimanganese decacarbonyl (Mn2(CO)10) in combination with organichalides is reported. The radicals formed through halogen abstraction byphotochemically generated manganese pentacarbonyl from organic halideswith high quantum efficiency initiate the polymerization of acrylic resins. Thekinetics of the process using various halide-containing molecules in thephotoinitiaiting system are investigated with real-time fourrier transforminfrared spectroscopy and photo-differential scanning calorimetry analyses,and the characteristics of 3D printouts are presented and compared with thatof the commercial photoinitiator, 2,4,6-trimethylbenzoyl)phosphine oxidewithout Mn2(CO)10. The results obtained confirm that the combination ofMn2(CO)10and structurally diverse organic halides is a class of promising 3Dsystem for various applications.
- Record ID
- CUT14ff46966f304f28b0a312e36c7d54ac
- Publication categories
- ;
- Author
- Journal series
- Macromolecular Rapid Communications, ISSN 1022-1336, e-ISSN 1521-3927
- Issue year
- 2023
- Vol
- 44
- No
- 3
- Pages
- [1-5]
- Article number
- 2200661
- Other elements of collation
- fot.; schem.; tab.; wykr.; Bibliografia (na s.) - 4-5; Bibliografia (liczba pozycji) - 43; Oznaczenie streszczenia - Streszcz. ang.; Data udostępnienia on-line - 2022-09-22; Numeracja w czasopiśmie - Vol. 44, Iss. 3
- Keywords in English
- 3D printing, manganese carbonyl, photoinitiators, photopolymerization, visible light
- ASJC Classification
- ; ;
- DOI
- DOI:10.1002/marc.202200661 Opening in a new tab
- URL
- https://onlinelibrary.wiley.com/doi/10.1002/marc.202200661 Opening in a new tab
- Related project
- Synteza i badania spektroskopowe nowych rozpuszczalnych w wodzie fotoinicjatorów wolnorodnikowych dedykowanych do otrzymywania mikrofabrykowanych struktur hydrożelowych jako pozakomórkowej matrycy do biodruku 3D w świetle widzialnym. . Project leader at PK: , ,
- Molecular design, synthesis and application of photoinitiator-catalysts (PICs) for photopolymerization reactions. . Project leader at PK: , ,
- Synteza i badania spektroskopowe nowych rozpuszczalnych w wodzie fotoinicjatorów wolnorodnikowych dedykowanych do otrzymywania mikrofabrykowanych struktur hydrożelowych jako pozakomórkowej matrycy do biodruku 3D w świetle widzialnym. . Project leader at PK: , ,
- Language
- eng (en) English
- Score (nominal)
- 100
- Score source
- journalList
- Score
- Publication indicators
- Additional fields
- Indeksowana w: Web of Science, Scopus
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUT14ff46966f304f28b0a312e36c7d54ac/
- URN
urn:pkr-prod:CUT14ff46966f304f28b0a312e36c7d54ac
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.