Difunctional 1H-quinolin-2-ones as spectroscopic fluorescent probes for real-time monitoring of photopolymerisation process and photosensitizers of fluorescent photopolymer resin in 3D printing
Authors:
- Monika Topa,
- Filip Petko,
- Mariusz Galek,
- Magdalena Jankowska,
- Roman Popielarz,
- Joanna Ortyl
Abstract
Herein, novel 1H-quinolin-2-ones derivatives dedicated to polymer chemistry have been reported. Essential spectroscopic studies including absorbance, fluorescence emission and excitation spectra were carried out. Subsequently, a number of studies on the suitability of new compounds for the role of fluorescent molecular probes using Fluorescence Probe Technology were performed. The research present also the suitability of these compounds as co-initiators in a two-component system: 1H-quinolin-2-ones/4,4′-dimethyl-diphenyl iodonium hexafluorophosphate (OMNICAT 440). Cationic photopolymerisation processes of CADE epoxy and vinyl TEGDVE monomers, free-radical photopolymerisation of TMPTA acrylic monomer as well as thiol-ene photo-polymerisation of a mixture of monomers: TATATO/MERCAPTO when exposed to UV light with maximum emission at 365 nm and visible light with maximum emission at 405 nm were carried out. Finally, the appli-cability of novel initiating systems to obtain fluorescent 3D prints was introduced.
- Record ID
- CUTfeaaedfc76bc43ecb4784174e7973df5
- Publication categories
- ;
- Author
- Journal series
- European Polymer Journal, ISSN 0014-3057, e-ISSN 1873-1945
- Issue year
- 2021
- Vol
- 156
- Pages
- [1-16]
- Article number
- 110612
- Other elements of collation
- fot.; schem.; tab.; wykr.; Bibliografia (na s.) - 15-16; Bibliografia (liczba pozycji) - 65; Oznaczenie streszczenia - Abstr.; Numeracja w czasopiśmie - Vol. 156
- Keywords in English
- fluorescent molecular sensors, photopolymerisation, fluorescence probe technology, photosensitizer, cationic photopolymerisation, free-radical photopolymerisation, thiol-ene photopolymerisation, 3D printing
- DOI
- DOI:10.1016/j.eurpolymj.2021.110612 Opening in a new tab
- URL
- https://www.sciencedirect.com/science/article/pii/S0014305721003463 Opening in a new tab
- Related project
- Synteza bimolekularnych fotoinicjatorów kationowych i badania mechanistycznych aspektów fotogenerowania mocnych kwasów protonowych w procesach synergistycznego oddziaływania soli oniowych oraz fotosensybilizatorów lub koinicjatorów. . Project leader at PK: , ,
Projects financed by NSC [Projekty finansowane przez NCN] - Synthesis and photochemistry/photophysics studies of the intelligent luminescent molecular sensors for selective detection in biochemistry and chemistry. . Project leader at PK: , ,
- Synteza bimolekularnych fotoinicjatorów kationowych i badania mechanistycznych aspektów fotogenerowania mocnych kwasów protonowych w procesach synergistycznego oddziaływania soli oniowych oraz fotosensybilizatorów lub koinicjatorów. . Project leader at PK: , ,
- Language
- eng (en) English
- License
- Score (nominal)
- 100
- Publication indicators
- Additional fields
- Indeksowana w: Web of Science, Scopus
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUTfeaaedfc76bc43ecb4784174e7973df5/
- URN
urn:pkr-prod:CUTfeaaedfc76bc43ecb4784174e7973df5
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.