Solubility products and solubility concepts
Authors:
- Anna Maria Michałowska-Kaczmarczyk,
- Aneta Spórna-Kucab,
- Tadeusz Michałowski
Abstract
The chapter refers to a general concept of solubility product Ksp of sparingly soluble hydroxides and different salts and calculation of solubility of some hydroxides, oxides, and different salts in aqueous media. A (criticized) conventional approach, based on stoichiometry of a reaction notation and the solubility product of a precipitate, is compared with the unconventional/correct approach based on charge and concentration balances and a detailed physicochemical knowledge on the system considered, and calculations realized according to generalized approach to electrolytic systems (GATES) principles. An indisputable advantage of the latter approach is proved in simulation of static or dynamic, two-phase nonredox or redox systems.
- Record ID
- CUT6a0e990102f44cfca3ece4f3102a7c5d
- Publication type
- Publication categories
- ; ;
- Author
- Pages
- 93-134
- Other elements of collation
- rys.; tab.; wykr.; Bibliografia (na s.) - 127-134; Bibliografia (liczba pozycji) - 97; Oznaczenie streszczenia - Abstr.
- Book
- Akitsu Takashiro Takashiro Akitsu (eds.): Descriptive inorganic chemistry researches of metal compounds, 2017, Rijeka, IntechOpen, ISBN 978-953-51-3398-8 (online)
- Keywords in English
- electrolytic two-phase systems, solubility, dissolution, static systems, dynamic systems, computer simulation, GATES, GEB
- DOI
- DOI:10.5772/67840 Opening in a new tab
- URL
- https://www.intechopen.com/books/descriptive-inorganic-chemistry-researches-of-metal-compounds Opening in a new tab
- Language
- eng (en) English
- License
- Score (nominal)
- 5
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUT6a0e990102f44cfca3ece4f3102a7c5d/
- URN
urn:pkr-prod:CUT6a0e990102f44cfca3ece4f3102a7c5d
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.