Novel terpolymers containing carbazole, coumarin and Alq3 complexes
Authors:
- Dariusz Bogdal,
- Mateusz Galica
Abstract
In this paper, the synthesis of terpolymers bearing carbazole, coumarin and 8-hydroxyquinoline moiety as pendant groups with content of coumarin and 8-hydroxyquinoline between 0.5 and 4 mol% was elaborated. Then the terpolymers underwent complexation reactions with aluminum bis(8-hydroxyquinoline)isopropoxylate (Alq2ispr) to form polymeric hybrid materials with aluminum tris(8-hydroxyquinoline) (Alq3) as side groups. The presence of carbazole, coumarin (MK) and 8-hydroxyquinoline (QM) as well as Alq3 in the terpolymers was confirmed by NMR, UV, photoluminescence, and size exclusion chromatography. The results indicates that these hybrid polymers have moderate molecular weights and solubility in common organic solvents. For photoluminescence spectra, an evidence for energy transfer from carbazole to coumarin and Alq3 groups was observed and highest relative fluorescence intensity was exhibited by solutions of the terpolymers containing the lowest content of MK, QM and Alq3.
- Record ID
- CUTc80c107576034c0faea4e7207db59942
- Publication categories
- ; ;
- Author
- Journal series
- Pure and Applied Chemistry, ISSN 0033-4545, e-ISSN 1365-3075
- Issue year
- 2019
- Vol
- 91
- No
- 3
- Pages
- 497-508
- Other elements of collation
- schem.; tab.; wykr.; Bibliografia (liczba pozycji) - 30; Oznaczenie streszczenia - Abstr.; Numeracja w czasopiśmie - Vol. 91, Iss. 3
- Conference
- 17th [International Conference on] Polymers and Organic Chemistry (POC-17), 2018, 04-06-2018 - 07-06-2018, Le Corum, Montpelier, Francja
- Keywords in English
- energy transfer, free-radical copolymerization, hybrid polymers, luminescence, methacrylates, POC-17
- DOI
- DOI:10.1515/pac-2018-1018 Opening in a new tab
- URL
- https://www.degruyter.com/view/j/pac.2019.91.issue-3/pac-2018-1018/pac-2018-1018.xml Opening in a new tab
- Language
- eng (en) English
- Score (nominal)
- 140
- Publication indicators
- = 1
- Additional fields
- Indeksowana w: Web of Science, Scopus
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUTc80c107576034c0faea4e7207db59942/
- URN
urn:pkr-prod:CUTc80c107576034c0faea4e7207db59942
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.