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Triethylsulfonium and triethylphosphonium cations as novel catalysts for the decomposition process of nitroethyl benzoates
Authors:
- Agnieszka Kącka,
- Radomir Jasiński
Abstract
A quantum chemical study of the decomposition reactions of nitroethyl benzoates catalyzed by triethylsulfonium and triethylphosphonium cations was carried out using various DFT theory levels. It was found that these reactions take place according to a one-step but polar mechanism, and much faster than the uncatalyzed process.
- Record ID
- CUT6a5b8b312ac244abb38fc09ef684c8d8
- Publication categories
- ;
- Author
- Journal series
- Phosphorus Sulfur and Silicon and the Related Elements, ISSN 1042-6507, e-ISSN 1563-5325
- Issue year
- 2017
- Vol
- 192
- No
- 12
- Pages
- 1252-1258
- Other elements of collation
- rys.; schem.; tab.; wykr.; Bibliografia (na s.) - 1257-1258; Bibliografia (liczba pozycji) - 69; Oznaczenie streszczenia - Abstr.; Numeracja w czasopiśmie - Vol. 192, Iss. 12
- Keywords in English
- thermal elimination, DFT study, nitroalkene, triethylsulfonium cation, triethylphosphonium cation
- DOI
- DOI:10.1080/10426507.2017.1290626 Opening in a new tab
- URL
- http://www.tandfonline.com/doi/abs/10.1080/10426507.2017.1290626 Opening in a new tab
- Related project
- Zastosowanie cieczy jonowych w syntezie organicznej. . Project leader at PK: , ,
Działalność statutowa - Language
- eng (en) English
- Score (nominal)
- 15
- Additional fields
- Indeksowana w: Web of Science, Scopus
- Uniform Resource Identifier
- https://cris.pk.edu.pl/info/article/CUT6a5b8b312ac244abb38fc09ef684c8d8/
- URN
urn:pkr-prod:CUT6a5b8b312ac244abb38fc09ef684c8d8
* presented citation count is obtained through Internet information analysis, and it is close to the number calculated by the Publish or PerishOpening in a new tab system.